There is no general rule for making adjectives. We know they are adjectives usually by what they do (their function) in a sentence. However, some word endings (suffixes) are typical of adjectives.
suffix  | examples  | 
-able, -ible  | comfortable, readable, incredible, invisible  | 
-al, -ial  | comical, normal, musical, industrial, presidential  | 
-ful  | beautiful, harmful, peaceful, wonderful  | 
-ic  | classic, economic, heroic, romantic  | 
-ical  | aeronautical, alphabetical, political  | 
-ish  | British, childish, Irish, foolish  | 
-ive, -ative  | active, alternative, creative, talkative  | 
-less  | endless, motionless, priceless, timeless  | 
-eous, -ious, -ous  | spontaneous, hideous, ambitious, anxious, dangerous, famous  | 
-y  | angry, busy, wealthy, windy  | 
Adjectives ending in -ic and -ical often have different meanings:
The economic policy of this government has failed.
A diesel car is usually more economical than a petrol one.