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Bonds Glucose Energy Glycosidic Alpha Bonding Side Hydrogen

Front Relate structural properties to the functions of starch wrt solubility, size, bonding and presence of side chains.
Back Solubility & Size
  • Insoluble - does not affect water potential & does not cause osmotic swell
  • Too large of a molecule, overcomes water's hydrogen bonds attempting to separate the molecules (amylose - 300 glucose molecules, amylopectin - 3000 glucose molecules)
  • Makes it good for storage - stays inside the plant cells without dissolving into the system
  • Many glucose units stored in one molecule - more energy dense than storing them separately



Bonding & Side chains
  • Amylose - only alpha 1,4 glycosidic bonds which have a bond angle that makes it form a helical structure further stabilised by intramolecular hydrogen bonds (between -OH groups between neighboring monomers) meaning it is more compact than if a straight chain - energy dense
  • Amylopectin - alpha 1,4 glycosidic bonds, every ~20C - alpha 1,6 glycosidic bond which forms a branched structure of helical chains - even more energy stored
  • 1,6 glycosidic bonds allow for more branch endings for enzyme activity - easy to hydrolyse and release the glucose for energy quickly

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